Tuesday, 11 January 2011

Tuesday, 27 July 2010

Hellsing






Hellsing is a Japanese manga series written and illustrated by Kouta Hirano. It first premiered in Young King Ours in 1997 and ended in September 2008. The individual chapters are collected and published in tankobon volumes by Shōnen Gahosha. As of March 2009 all chapters have been released in 10 volumes in Japan. Hellsing chronicles the efforts of the mysterious and secret Hellsing Organization, as it combats vampires, ghouls, and other supernatural foes who threaten England.

The manga series is licensed for English language release in North America by Dark Horse Comics, in Australia and New Zealand by Madman Entertainment, and in Singapore by Chuang Yi. In 2001, Hirano began publishing chapters of a prequel series, Hellsing: The Dawn, in special editions of Young King OURs, with six chapters released as of September 2008.

An anime series of the same name was produced by Gonzo. Directed by Umanosuke Iida, the series was based on the manga, but used a screenplay by Chiaki Konaka and is significantly different from the manga in terms of plot, though it uses some of the same characters and similar character designs. Spanning 13 episodes, it was broadcast on Japan's Fuji Television from October 10, 2001 to January 16, 2002.

An original video animation entitled Hellsing Ultimate is being produced by Satelight and Geneon. It follows the manga storyline more closely than the anime series. The first episode was released in Japan on February 10, 2006, and as of December 2009, seven episodes have been released. The sixth OVA in the series will be available on both DVD and Blu-Ray, with Blu-Ray editions of episodes one through five due out sometime in 2010. The first episode was released in North America on December 5, 2006. So far only four episodes of the OVA have been released in North America.

Friday, 5 February 2010

Exclusive Interview: Zuzanna Szadkowski (Dorota) of 'Gossip Girl'

Exclusive Interview: Zuzanna Szadkowski (Dorota) of 'Gossip Girl'


Zuzanna Szadkowski, better known as Blair Waldorf's maid Dorota on Gossip Girl, had no idea when she signed on for the minor role that it would make such a major impact--on the show, the fans, and her life as an actress.

"I feel blessed," she told us when we had the chance to chat with her about the part, and the positive reactions it has elicited among the show's viewers. "I'm thrilled and surprised every time I meet a Dorota fan."

Zuzanna might be surprised by Dorota's popularity, but we're certainly not. On a show that often crams a week's worth of high-stakes drama into one hour, Dorota is more than just a maid: she's our essential comic relief; the brief exhales between Gossip Girl's frenzied sessions of passion, deceit, mortification, and the other outlandish growing pains undergone by its young, beautiful and affluent stars. It helps to have Dorota, to balance out all that turmoil. And it helps even more that she's hilarious.

We had the chance to ask some of your fan questions for "Dorota," plus a few of our own. Our full Q & A with the lovely Zuzanna Szadkowski, after the jump.

Has Dorota learned about the Upper East Side from Blair, or has Blair learned from Dorota?

Oh, man. I don't know. I think that they certainly do teach each other a lot, but I think just being around Miss Blair and around her crew gives Dorota a real insight into a life that otherwise she might not know anything about. I think she always has her eye out, so anything that goes on doesn't get past her.

Will Dorota be getting any steamy scenes with everyone's favorite doorman, Vanya?

I don't know. We'll have to watch and see what happens with them, but I just think that Vanya is the cutest. I'm really psyched for Dorota when their relationship started to blossom in the Chasing Dorota webisodes. I was like, "Go, girl! He's so cute!"

Where did the idea for the Chasing Dorota webisodes come from?

I'm not sure. I don't know exactly where it was born. But when we began shooting them, for me it was like a dream come true. I was like pinching myself. I just thought they were so funny and so well-written. And they gave me a chance to explore a little bit more of Dorota's backstory and her personal life, and her life outside of Miss Blair. So it was really exciting, and I think they turned out so well. And I'd like to mention that they are available now in the Bonus Features in the Season 2 DVD. It's like a little treat on that DVD for viewers.

Did you know when you started this that you would be playing a character who would become so popular?

No. You know what, I was really excited to get the part because I just knew the show was going to be cool. Just the association with a show that was so hot was really thrilling for me. But I had no idea that Dorota would turn out to be so cool, and such a sort of dream-part for me. It was a really pleasant surprise, and I'm so happy that she's well-received by fans. I'm thrilled and surprised every time I meet a Dorota fan.

Have you had any crazy Dorota fan experiences?

Not crazy ones. I have a lot of fun ones. I guess the only crazy thing is that sometimes Gossip Girl fans are not who you'd expect them to be. I've had some really interesting characters come up to me and be like, "Oh, I watch you on the show!" I always laugh about this time that I was walking down the street, and this guy in a three-piece suit, he was obviously some kind of banker or Wall Street guy, and he was like, "Dorota!" That, to me, was fun, because fans come in all shapes and sizes, so that's exciting. I get a kick out of it when I meet fans, or even on Twitter, when I make fan connections on Twitter, I just really enjoy it, because I feel blessed that people are liking the character.

Dorota's Polish, and you're Polish. Are people surprised to hear that you don't actually have an accent in real life when they meet you?

Yeah, actually, that's the weirdest part. I don't usually wear a bun or an apron when I go out, and I don't have an accent, so it's not so easy to spot me. I think it definitely takes people by surprise, which I'm very happy about, because I want the accent to come off in an authentic fashion. But, you know, it is my heritage. I was born Poland. My parents actually have very thick accents, so it is definitely pulled from personal experience. I have consulted my mom several times on a little turn of phrase, here and there. So I certainly have that resource right at my fingertips.

What's your favorite Dorota line?

There was that really awesome Dorota scene, I thought, in an episode where Blair was having a dream, and was interrupted, and she woke up, and Dorota kind of caught her in the middle of this dream, and I think the line was, "God is always watching." But I just thought that was hysterical, and the writers are so awesome. I always get such a kick out of it when I open the script and I see that Dorota has something funny and amazing like that to say. I always kind of jump around a little bit.

Which character or cast member do you wish Dorota had more interaction with?

I feel like over the course of the seasons, Dorota has had a chance to kind of bump into most everyone. I definitely like being in scenes with Mister Chuck and Miss Blair. I think those scenes are always exciting, so that's kind of my favorite combination to work in.

Can you hint at anything about the drama coming up for Blair and Dorota?

I don't know what's coming, so I don't have any secrets to spill. But I've been watching this season as a fan myself, and I just feel like all the surprises of this new college lifestyle are really exciting, and it's a new twist and turn every week. So, we just have to keep watching and see.

What would be your dream Dorota storyline?

I am partial to scenes in which Dorota gets to leave the penthouse and walk around, so I love, for example, in the Lily and Rufus wedding, where Dorota got to wear a big hat and a flowered dress. Those departures are more fun for me, so I always look for that, to see Dorota out of her usual garb and on the streets of New York. Out and about is always exciting for me, no matter what's going on. I also like to shoot on location, because I get a chance to see the connection between New York City and the show, and the New York energy that is so important to Gossip Girl. So I like being able to be a part of that during location shoots.

You've also helped out with the Gossip Girl fan tours around New York City. What was that like?

It was cool! I got to go on the tour bus, so I saw all of these real places where Gossip Girl happens, and the fans were really fun. They were international fans, from all over the place, so I got to experience the world of Gossip Girl like they did. It's amazing, because I feel like we need a New York show always, and this is our new, gorgeous New York show. Going to these locations on the Upper East Side, and the steps of the Met, and all of these places are so beautiful in New York that it just makes me happy to be a New Yorker. To take the tour, I was just enamored all over again by this city.

So you're an actual New Yorker?

I count myself as one. I was born in Poland, and I was raised in the Midwest, in Indiana. And I came here a long time ago to go to college. So I've been living here, and I live in Brooklyn. So I definitely consider myself to be a New York gal.

What has been your favorite storyline of this season so far?

I'm partial to the activities of Blair, so I've actually really liked watching the Blair-Chuck blossoming in this new phase of college transition, and watching Blair finding her place, finding her way at NYU. Her new trials and tribulations. But I really like her journey so far. I think that Leighton Meester is such an incredible actor, and so I am just drawn to her work, and I feel like it just gets better and better all the time.

Wednesday, 11 November 2009

hetalia

Hetalia: Axis Powersis a webcomic, later adapted as a manga and an anime series, by Hidekaz Himaruya . The series presents an allegorical interpretation of political and historic events, particularly of the World War II era, in which the various countries are represented byanthropomorphic characters. Hetalia is a pun combining hetare.
[1] This is to make light of Italy's apparent cowardice during World War II.Himaruya originally created Hetalia as an online webcomic, and so far two tankōbon have been published by Gentosha Comics, the first on March 28, 2008 and the second on December 10, 2008. The series was later adapted into drama CDs, and an anime series created by Studio Deenhas also begun streaming online.The main historical events portrayed in this work occur between World War I and World War II. The series often uses satire and comedy to address well-known and lesser-known historical facts alike. Historical political and military interaction between countries is represented in Hetalia as social and romantic interaction between the characters; the webcomic version in particular depicts military and economic incursions using innuendo.

Sunday, 31 May 2009

halibel bleach

halibel bleach

Halibel is a hot role in bleach,and many people like to cosplay Halibel.Here are some halihel cosplay photos.If you like much more ,you can goto www.cosplayfu.com.There will be more cosplay photos that you like.





gundam cosplay

I had shared some gundam  cosplay photos ----- Gundam Seed. They are all beautiful and professional.You can see more high quality cosplay photos in www.cosplayfu.com





Monday, 4 May 2009

結合軌道

2-1.電子と原子と分子と原子の結合

 「0-1.固体って何からできているの?」に書いたとおり、およそ物質というのは原子の集合体ですが、ここではもう少しつっこんだ話をしてみましょう。
 まず、原子そのまま、原子1個が孤立した状態で安定に存在する元素はあるのか?ですが、皆さんどう思いますか?110種類以上の原子(元素)が現在知られていますが、その殆どは同種(例えば酸素O2)あるいは異種の他の原子とくっついて存在しています。でも実はほんの数種類だけ原子1個で安定に存在する元素があります。これらは常温(室温)では全て無色の気体ですから目には見えませんが、希ガスと呼ばれるヘリウム、ネオン、アルゴン、クリプトン等がそうです。左図にはネオンの原子を模式的に書いてありますが、このような希ガスは電子の数が「ちょうど良い」 ため、そこに余計に電子を加えたりそこから電子を1個抜いたイオン状態になってもエネルギーが得をしません。だから中性でしかも1原子で気体として存在す るのです。ここで電子のエネルギーがなぜとびとびなのか、また希ガス原子の電子数だけ詰まった状態から上がえらく離れているのか、というのをしっかり理解 するには量子力学を学んでシュレーディンガー方程式を解いてみないといけないのですが、ここではまあそんなもんか、原子の電子数が2、10、18、36だ と安定なんだなと思って下さい(これらの数字を2で割ると1、1+1+3=5、1+1+3+1+3=9、1+1+3+1+3+5+1+3=18となりま す。このたし算の意味もシュレーディンガー方程式をとくとわかります)。

 さて、単体で安定な原子があるからなんなんだという事ですが、他の多くの原子・元素は少しでも上の希ガスのような状態になろうとして他の原子・元素とくっつくと いうのが物質の成り立ち・起源を考える上で基本的かつ重要なことなのです。これは化学で出てくる結合ってやつですね。で、くっつく方法ですが元の中性原子 の電子数が希ガスのそれに近い場合はてっとり早くよその原子から電子を奪い取るか、逆によその原子に電子を放出することになります。この場合当然相性の良 い相手と手を組むのが理想的になるわけで、その顕著な例が食塩(塩化ナトリウムNaCl)になります。ナトリウムNaは電子を1個放出すると、塩素Clは電子を1個もらうと、それぞれ電子数がネオン、アルゴン原子と同じになり、電子のエネルギーとしては安定な状態になります。しかしそうなると両方ともイオンとなり帯電します。帯電した状態では必ず正なら負、負なら正に帯電した物を引きつけますので、この両者の間で電子のやり取りをした場合は必ず一緒にいるということになり、固体の場合は交互に規則正しく並んだ配置をとった結晶になります。このような結合をイオン結合と呼びます。また、このような固体は水に溶けやすいという性質がありますが、この場合でも水溶液中に同数のイオンがそれぞれとけている訳です。

 では全ての物質は食塩みたいなのか、というとそうなっていなさそうなことは普段の生活から想像できますね。ナト リウムや塩素(前者をアルカリ金属と呼び他にカリウムK、セシウムCsという元素があります。後者はハロゲンと呼ばれ他にフッ素F、臭素Brが似た元素で す)みたいに電子1個だけやりとりすれば済む元素ばかりではありません。例えば窒素原子Nは3個電子が足りないので、なかなかイオン結合で他の原子・イオンとくっつく訳にはいきません。ではどうするのか、というと結果として「ほとんど無害な気体」として存在するのですが、この場合は窒素原子2つ、すなわち同じ元素とペアを組みます。その様子をやはり図に示していますが、窒素原子中の「外側の電子軌道」が接する・交差するまでに互いに原子が近づき、その結果それまで「1個の原子核のまわりをぐるぐる回っていた」電子のいくつかが「2この原子核のまわりをぐるぐるまわる」ようになります。そうなるとそれらの電子は「元々どっちの原子核をまわっていたか」は意味がなくなり、互いに軌道を共有することになります。こ のようないくつかの原子軌道を共有したような新たな軌道は、分子1かたまりでみると「分子に属している」ため分子軌道と呼ばれます。そして実は1つの分子 軌道には電子が「2個まで入ることができる」ので、取り合えず結合して電子の総数が偶数個になると希ガス程ではないにしても結構安定な状態になります。さ らに電子を「共有」することで、各々の原子核からみると希ガス分の電子がまわりにいることになって、やはり安定した状態でしかも帯電せず中性です。このよ うな結合を共有結合と呼びますが化学では窒素分子N2を表記する場合「共有する電子が3個あるよ」という事を示す為に上図のような書き方をすることもあります。酸素分子も同様な結合ですが、酸素原子の場合は足りない電子が2個と少し少ない為に他の元素から電子を合計で2個受け取って「酸化物」に なることも非常に多いです。高校の化学では共有結合の例として炭素と水素からなるメタンをよく例にあげられますが、これも共有結合の基本的な構成です。ち なみにこの共有結合というのは生命活動には極めて重要な役割を果たしています。というのもDNA、たんぱく質、脂肪といった体の重要な部分の分子の大部分 は炭素C、窒素N、リンP、酸素O、水素Hの間の共有結合から構成されているのですから。そして体内のいわゆるカロリー消費、食物の消化というのも殆どが 共有結合の変化による反応なのです。
 では原子間の結合というのは上の2種類で済むのかというともっと中途半端な電子数の元素も数多くあり、例えば鉄Feなんていうのはその最たる例です。実はこういう元素の多くが「金属」であり、固体では単体金属もしくは合金として存在します。それを金属結合と呼ぶのですがどういう結合なのかは次のページで説明することにしましょう。

(ちょっと大学生向けな話)窒素が酸素よりも安定な理由: 上記の説明は量子力学(化学の分野では量子化学と言います)を少し学んでおくとかなり分かりやすくなります。中性窒素原子の電子配置は(1s)2(2s)2(2p)3で p軌道の数と電子の数が3つで同じです。2原子分子を作るときには2つの原子から3つのp軌道が参加して合計6個の分子軌道を作りますが、この分子軌道の うち3つは元の原子軌道よりもエネルギーの低い結合軌道、残りの3つはエネルギーの高い反結合軌道になります。窒素分子では2p電子が合計6個あり、1つ の分子軌道には(互いに逆向きのスピンを持った)電子が2個入れますので、結果としてこれらの電子は全部結合軌道に入り、結合軌道は全て電子が詰まった状態になり、安定になります。これに対して酸素分子の場合中性酸素原子の電子配置が(1s)2(2s)2(2p)4、分子になると窒素よりも電子が2個多い為反結合軌道にも電子が詰まります。そうすると窒素の時に比べて酸素の時のほうが結合した時のエネルギーの利得が少ないことになり、それゆえに酸素分子は比較的他の物質、元素と反応(これが酸化)しやすくなります。